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Focused Interest Group on MicroAnalytical Standards
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Information on Standards and Reference Materials (S-RM)

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Benitoite (silicate) - ID NMNH 86539

First entry: 01/02/16 || Last update: 27/07/21 || Status: acceptedOK

General information
Mineral class
   Sub-class
   Group
   Species
Silicate
   Cyclosilicate
   Benitoite group
   Benitoite
Synthetic? no
Formula
Standard element(s)
BaTiSi3O9
Ba Ti Si
Origin, rock type... San Benito Co., California, USA

EDS spectrum & images

No images found...

Available analysis/-es

(*) Recommended analysis.

Analysis 1
Recommended analysis
ReferenceJ. Nelen
Analysis typeunknown
Wt-% oxideWt-% elementAtomic
43.7501
19.3500
37.0500
SiO2
TiO2
BaO
20.4506
11.5974
33.1840
34.9181
Si
Ti
Ba
O
3.00374
0.99945
0.99681
9.00318
100.150100.15014.003
Analysis 2
See analysis 1 for recommended analysis
ReferenceJo Laird (CIT, UWH/UNH?)
MethodEMP (average or single point?), emission spectrometry
Analysis typeaverage
Analysis commentAnalysis from blue reference book at UMass Amherst labeled Benitoite BLUE; San Benito County (CA). Ba, Si, Ti by microprobe analysis; Al, Fe, Ca by emission spectrometry.
Wt-% oxideWt-% elementAtom: N/A
43.26
19.56
0.20
0.05
0.10
37.22
SiO2
TiO2
Al2O3
FeO
CaO
BaO
20.221
11.724
0.106
0.039
0.071
33.336
34.893
Si
Ti
Al
Fe
Ca
Ba
O
100.390100.390
Analysis 3
See analysis 1 for recommended analysis
ReferenceJo Laird (CIT, UWH/UNH?)
MethodEMP (average or single point?), emission spectrometry
Analysis typeaverage
Analysis commentAnalysis from blue reference book at UMass Amherst labeled Benitoite WHITE; San Benito County (CA). Ba, Si, Ti by microprobe analysis; Al, Fe, Ca by emission spectrometry.
Wt-% oxideWt-% elementAtom: N/A
42.62
19.44
0.04
0.01
0.006
37.27
SiO2
TiO2
Al2O3
FeO
CaO
BaO
19.922
11.652
0.021
0.008
0.004
33.381
34.398
Si
Ti
Al
Fe
Ca
Ba
O
99.38699.386

Comments

The spectacular cathodoluminescence (see image above) of benitoite has been used for optimization of electron microbeam instruments for decades; Preliminary CL spectroscopy reveals a peak at about 420 nm.

References

  • Jarosewich, E., Nelen, J. A., and Norberg, J. A. (1980) Reference Samples for Electron Microprobe Analysis. Geostandards Newsletter 4, p. 43-47

Providers and purchase options

Smithsonian Institution
PO Box 37012
SI Building, Room 153, MRC 010
Washington, D.C. 20013-7012
USA
https://mineralsciences.si.edu/facilities/standards.htm
Material: mineral (size: > 1.19 mm, 1.0 mm - 0.5 mm, < 0.5 mm)
https://naturalhistory.si.edu/research/mineral-sciences/collections-overview/reference-materials/smithsonian-microbeam-standards


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